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Blasts were heard in Kyiv and several buildings were set ablaze after Russia targeted Ukraine's capital for the third night running.
Officials say falling debris caused the blazes, as Ukraine's air defences targeted incoming projectiles. At least one person is reported killed.
Ukraine says it downed all missiles and drones used in Russia's previous two night-time attacks.
President Volodymyr Zelensky has praised US-made Patriot air defences.
He said they ensured "100% downing of any Russian missiles".
"Russia wants to follow the path of evil to the end, that is, to its defeat, because evil cannot have any other end but defeat," he said in a video address late on Monday.
"The world must see that terror is losing."
Russia's military has said that all intended targets were hit during its recent attacks on Kyiv and other Ukrainian cities.
The claims by the warring sides have not been independently verified.
Kyiv's military administration reported three buildings on fire in the latest overnight air assault.
In the southern Holosiivskyi district, one person was killed and three injured as a fire started in a multi-storey building.
"Two upper floors are destroyed, and there may be people under the rubble," the administration said in a statement.
Two private buildings were ablaze and several cars damaged in the Darnytskyi district - just across the Dnipro river.
Kyiv Mayor Vitaliy Klitschko described the latest attack as "massive", urging residents "not to leave shelters".
The air raid alert was lifted after several hours, meaning that the Russian air assault was over for the time being.
It was the 17th attack on the capital since the beginning of May, including a rare daytime attack on Monday.
Russia - which launched its full-scale invasion in February 2022 - has been using kamikaze drones as well as a range of cruise and ballistic missiles.
Analysts say Moscow is seeking to deplete and damage Ukraine's air defences ahead of its long-expected counter-offensive.
Ukraine has been planning a counter-offensive for months. But it has wanted as much time as possible to train troops and to receive military equipment from Western allies.